<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-00534362</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-04-28T10:39:02+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Crystallisation of cellulose/N-methylmorpholine-N-oxide hydrate solutions</title>
            <author role="aut">
              <persName>
                <forename type="first">Olga</forename>
                <surname>Biganska</surname>
              </persName>
              <idno type="halauthorid">434793-0</idno>
              <affiliation ref="#struct-1158"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Patrick</forename>
                <surname>Navard</surname>
              </persName>
              <email type="md5">05302c9b89963aa61565ca654d8cd97d</email>
              <email type="domain">mines-paristech.fr</email>
              <idno type="idhal" notation="string">patrick-navard</idno>
              <idno type="idhal" notation="numeric">11676</idno>
              <idno type="halauthorid" notation="string">11124-11676</idno>
              <idno type="IDREF">https://www.idref.fr/030801060</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-8264-6507</idno>
              <affiliation ref="#struct-1158"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Olivier</forename>
                <surname>Bédué</surname>
              </persName>
              <idno type="halauthorid">505457-0</idno>
              <affiliation ref="#struct-131767"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Corinne</forename>
                <surname>Matarasso</surname>
              </persName>
              <email type="md5">aa86f06f21f9137f85868e1a92bf2f0a</email>
              <email type="domain">mines-paristech.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2010-11-09 14:06:46</date>
              <date type="whenWritten">2002</date>
              <date type="whenModified">2026-04-28 10:38:58</date>
              <date type="whenReleased">2010-11-09 14:06:46</date>
              <date type="whenProduced">2002</date>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="156114">
                <persName>
                  <forename>Corinne</forename>
                  <surname>Matarasso</surname>
                </persName>
                <email type="md5">aa86f06f21f9137f85868e1a92bf2f0a</email>
                <email type="domain">mines-paristech.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-00534362</idno>
            <idno type="halUri">https://minesparis-psl.hal.science/hal-00534362</idno>
            <idno type="halBibtex">biganska:hal-00534362</idno>
            <idno type="halRefHtml">&lt;i&gt;Polymer&lt;/i&gt;, 2002, 43 (23), p. 6139-6145</idno>
            <idno type="halRef">Polymer, 2002, 43 (23), p. 6139-6145</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="ENSMP" corresp="PARISTECH">MINES ParisTech</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="ENSMP_CEMEF" corresp="ENSMP">Mise en forme des matériaux (CEMEF)</idno>
            <idno type="stamp" n="PARISTECH">ParisTech</idno>
            <idno type="stamp" n="PSL">Université Paris sciences et lettres</idno>
            <idno type="stamp" n="ENSMP_DEP_MM" corresp="ENSMP">Département Mécanique et Matériaux</idno>
            <idno type="stamp" n="ENSMP_DR" corresp="ENSMP">ENSMP_DR</idno>
            <idno type="stamp" n="ENSMP_CEMEF_BIO" corresp="ENSMP_CEMEF">Polymères &amp; Composites Biosourcés (CEMEF)</idno>
            <idno type="stamp" n="ENSMP-PSL" corresp="PSL">MINES ParisTech - École nationale supérieure des mines de Paris - PSL</idno>
            <idno type="stamp" n="ENSMP_CEMEF_SP" corresp="ENSMP_CEMEF">Surfaces et Polymères - S&amp;P</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Crystallisation of cellulose/N-methylmorpholine-N-oxide hydrate solutions</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Olga</forename>
                    <surname>Biganska</surname>
                  </persName>
                  <idno type="halauthorid">434793-0</idno>
                  <affiliation ref="#struct-1158"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Patrick</forename>
                    <surname>Navard</surname>
                  </persName>
                  <email type="md5">05302c9b89963aa61565ca654d8cd97d</email>
                  <email type="domain">mines-paristech.fr</email>
                  <idno type="idhal" notation="string">patrick-navard</idno>
                  <idno type="idhal" notation="numeric">11676</idno>
                  <idno type="halauthorid" notation="string">11124-11676</idno>
                  <idno type="IDREF">https://www.idref.fr/030801060</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-8264-6507</idno>
                  <affiliation ref="#struct-1158"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Olivier</forename>
                    <surname>Bédué</surname>
                  </persName>
                  <idno type="halauthorid">505457-0</idno>
                  <affiliation ref="#struct-131767"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">16533</idno>
                <idno type="issn">0032-3861</idno>
                <title level="j">Polymer</title>
                <imprint>
                  <publisher>Elsevier</publisher>
                  <biblScope unit="volume">43</biblScope>
                  <biblScope unit="issue">23</biblScope>
                  <biblScope unit="pp">p. 6139-6145</biblScope>
                  <date type="datePub">2002</date>
                </imprint>
              </monogr>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">cellulose</term>
                <term xml:lang="en">N-methylmorpholine-N-oxide</term>
                <term xml:lang="en">crystallisation kinetics</term>
              </keywords>
              <classCode scheme="halDomain" n="spi.mat">Engineering Sciences [physics]/Materials</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>N-methylmorpholine-N-oxide (NMMO) hydrates are direct solvents for cellulose used commercially in the preparation of cellulose spinning dopes for fibre and film manufacturing. The fact that the cellulose/NMMO/water solutions can crystallise under cooling is important in the process of preparing fibres and films and in their structure formation. It is shown here that the major difference with classical polymer solutions is that the crystallisation of cellulose/NMMO/water solutions is only due to the crystallisation of the solvent, not of the cellulose. The reason for the decrease in crystallisation velocity with the increase in the cellulose concentration is the reduction in the crystallisable part of the solution. The concentration of water in solutions with the same cellulose content is found to strongly influence the crystallisation velocity and the morphology of crystallised solutions. The variation of the crystallisation velocity values with the type of cellulose can be explained by different amounts of free water bound to NMMO, that depend on the cellulose origin.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-1158" status="VALID">
          <idno type="IdRef">026523574</idno>
          <idno type="ISNI">0000 0001 0658 7015 </idno>
          <idno type="RNSR">199719336K</idno>
          <idno type="ROR">https://ror.org/00qm1ye08</idno>
          <orgName>Centre de Mise en Forme des Matériaux</orgName>
          <orgName type="acronym">CEMEF</orgName>
          <desc>
            <address>
              <addrLine>Rue Claude Daunesse CS 10207 06904 Sophia Antipolis cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cemef.mines-paristech.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301492" type="direct"/>
            <relation active="#struct-564132" type="indirect"/>
            <relation name="UMR7635" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-131767" status="INCOMING">
          <orgName>Spontex, Centre de Recherche</orgName>
          <desc>
            <address>
              <addrLine>74 rue St-Just-des-Marais 60026 Beauvais</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-331988" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-301492" status="VALID">
          <idno type="IdRef">026375249</idno>
          <idno type="ROR">https://ror.org/04y8cs423</idno>
          <orgName>Mines Paris - PSL (École nationale supérieure des mines de Paris)</orgName>
          <date type="start">1783-01-01</date>
          <desc>
            <address>
              <addrLine>60, boulevard Saint-Michel 75006 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.minesparis.psl.eu/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-564132" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-564132" status="VALID">
          <idno type="IdRef">241597595</idno>
          <idno type="ISNI">0000 0004 1784 3645</idno>
          <idno type="ROR">https://ror.org/013cjyk83</idno>
          <orgName>Université Paris Sciences et Lettres</orgName>
          <orgName type="acronym">PSL</orgName>
          <desc>
            <address>
              <addrLine>60 rue Mazarine 75006 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.psl.eu/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-331988" status="INCOMING">
          <orgName>Spontex</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>